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71.
Raja DS Paramaguru G Bhuvanesh NS Reibenspies JH Renganathan R Natarajan K 《Dalton transactions (Cambridge, England : 2003)》2011,40(17):4548-4559
Four 2-oxo-1,2-dihydroquinoline-3-carbaldehyde N-substituted thiosemicarbazone ligands (H(2)-OQtsc-R, where R = H, Me, Et or Ph) and their corresponding new copper(II) complexes [CuCl(2)(H(2)-OQtsc-H)]·2H(2)O (1), [CuCl(2)(H(2)-OQtsc-Me)]·2H(2)O (2), [CuCl(2)(H(2)-OQtsc-Et)(CH(3)OH)]Cl (3) and [CuCl(H-OQtsc-Ph)]·CH(3)OH (4) have been synthesized in order to correlate the effect of terminal N-substitution on coordination behaviour, structure and biological activity. Single crystal X-ray diffraction studies revealed that the complexes 1, 2 and 3 have square pyramidal geometry around the central metal ion. In the complexes 1 and 2, the copper ion is coordinated by the ligand with ONS donor atoms, one chloride ion in apical position and the other chloride in the basal plane. Complex 3 consists of [CuCl(2)(H(2)-OQtsc-Et)(CH(3)OH)](+) cation and a chloride as counter ion. The copper ion is coordinated by the ligand with ONS donor atoms and by one chloride ion in the basal plane. One methanol molecule is bonded through its neutral oxygen in the apical position. Complex 4 is square planar with the ligand coordinating through uni-negative tridentate ONS(-) and by one chloride ion in the basal plane. The binding of complexes with lysozyme protein was carried out by fluorescence spectroscopy. Investigations of antioxidation properties showed that all the copper(II) complexes have strong radical scavenging properties. The cytotoxicity of the complexes 3 and 4 against NIH 3T3 and HeLa cell lines showed that synergy between the metal and ligands results in a significant enhancement in the cell death with IC(50) of ~10-40 μM. A size dependence of substitution at terminal N in the thiosemicarbazones on the biological activities of the complexes has been observed. 相似文献
72.
Salacia oblonga, a woody climbing plant belonging to the family Celastaceae, is widely distributed in India and other southeast Asian countries. The genus Salacia have been used particularly for the treatment of diabetes, obesity, gonorrhoea, rheumatism, pruritus and asthma. Acetaminophen (APAP), used as an analgesic drug, produces liver and kidney necrosis in mammals at high doses. The aim of this study was to investigate the nephroprotective and antioxidant activities of the ethanol extract of Salacia oblonga (EESO) at the two dose levels of 250 and 500 mg/kg?bw on APAP-induced toxicity in rats. The results showed that APAP significantly increases the levels of serum urea, creatinine, and reduces levels of uric acid concentration. The EESO reduces these by increasing anti-oxidative responses as assessed by biochemical and histopathological parameters. In conclusion, our results suggest that the EESO possesses nephroprotective and antioxidant effects against APAP-induced nephrotoxicity in rats. 相似文献
73.
Four new partially fluorinated metal organic frameworks (HF-MOFs) have been synthesized under different solvothermal conditions (H(2)O or dimethylformamide (DMF)) from transition metal cations [Co(2+) and Mn(2+)], 3-methyl pyridine (3-mepy) and 4,4'-(hexafluoroisopropylidene) bis(benzoic acid) (C(17)H(10)F(6)O(4), H(2)hfbba), to determine the influence of reaction conditions on the formation of MOFs. This family of materials displays a striking degree of structural similarity depending on the solvent of synthesis. HF-MOFs synthesized from H(2)O [Co-HFMOF-W, Co(hfbba)(3-mepy)(H(2)O) and Mn-HFMOF-W, Mn(hfbba)(3-mepy)(H(2)O)] contain three-dimensional connectivity whereas HF-MOFs synthesized from DMF Co-HFMOF-D, [Co(2)(hfbba)(2)(3-mepy)(2)]·(DMF)(3) and Mn-HFMOF-D, [Mn(2)(hfbba)(2)(3-mepy)]·(H(2)O) are two-dimensional in nature. Co-HFMOF-W and Mn-HFMOF-W are iso-structural polymeric materials. Thermal gravimetric analysis performed on as-synthesized HF-MOFs revealed that these compounds have high thermal stability (~350 °C). The continuous decrease of the χT product with decreasing T for Co-HFMOF-D and Co-HFMOF-W respectively indicates the presence of antiferromagnetic exchange interaction between two Co(2+) (S = 3/2) metal centers within a cluster. 相似文献
74.
75.
The vacuum ultraviolet (VUV) absorption spectrum of difluoromethane (CH2F2) was studied using synchrotron radiation from the storage ring Indus-1, Indore, India. Spectra were recorded in the spectral region 1050–1500 Å (~8.3–11.8 eV) at a resolution of 1.5 Å. Three absorption band systems were observed in this region. Overall features observed are in good agreement with previously published work. Some discrepancies in assignments of the observed vibronic bands carried out by previous workers have been resolved. The observed bands have been classified in terms of Rydberg series. 相似文献
76.
77.
C.P. Bust J.R. Carter W.W. Neale J.G. Rushbrooke D.R. Ward R.E. Ansorge B.Y. Oh M. Pratap G. Sionakides G.A. Smith J. Whitmore R. Raja L. Voyvodic 《Nuclear Physics B》1978,140(3):409-422
We have investigated the reactions . The final state is dominated by diffractive production of a system which shows a strong tendency to form . The process is also observed in this reaction, indicating an energy dependence of s?1.5±0.1. The channel shows less single diffraction, and has a doubly diffractive component consistent with pomeron factorization. Strong Δ++(Δ++) production is agoain seen, but in contrast to the channel we also observe considerable ?0 production. 相似文献
78.
R.E. Ansorge J.R. Carter R.P. Mount W.W. Neale R. Raja J.G. Rushbrooke 《Nuclear Physics B》1975,97(3):439-444
We present data on the inclusive neutron spectra produced in the forward direction by the interactions of 23.85 GeV/c protons in a copper target. The results are in good agreement with the predictions of the triple-Regge model. 相似文献
79.
M. Yasin Akhtar Raja Wade N. Sisk Mohammad Yousaf David Allen 《Applied physics. B, Lasers and optics》1996,64(1):79-84
Experimental investigations of the photon’s B
(3)-field (third longitudinal polarization) are reported. The existence of an “axial magnetostatic field of photon” has been
predicted in B
π or B
(3)-theory as the fundamental property of the circularly polarized light, and reported in numerous papers and monographs. High-sensitivity
detection has been employed in photomagnetic induction, Faraday, and inverse Faraday effects (IFE) originating from such a
field. The results of all three experiments clearly disprove the claims of B
π-theory. Putting together these results and theoretical calculations in perspective, it is concluded that such fields are
non-existent.
Received: 25 January 1996 / Revised version: 24 May 1996 相似文献
80.
Raja R Golovko VB Thomas JM Berenguer-Murcia A Zhou W Xie S Johnson BF 《Chemical communications (Cambridge, England)》2005,(15):2026-2028
Nanoparticles of Co and NiPd, derived from colloidal precursors and supported on commercially available non-ordered mesoporous silica, are highly effective, cheap, recyclable and industrially viable catalysts for the hydrogenation of a range of nitro-substituted aromatics under mild conditions. 相似文献